I run my BMW Z3 on Super-Unleaded only, but as you are saying PDS it's becoming more difficult nowadays to find stations with an E5 pump.
I recently spoke to a forecourt attendant and he said they were not stocking it until the new pumps are installed - quite why it needs new pumps to dispense it, or whether it is accelerated decay of the rubber, etc in the current E5 pumps?
Either way, the benefits far outweight the extra cost of the E5 in my opinion.
Between 1500 and 2500 rpm the engine was always flat on acceleration....switched to E5 and its where it should be now - smooth as silk all through the rev ranges.
Not only the driveability of the car has transformed but the economy is much better too. I don't see going back to E10 has any benefit for older cars.
However, running E5 in my motorbikes seems to have very little noticable benefit that I can determine (as yet).